Olefin metathesis in air

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Olefin metathesis in air

Since the discovery and now widespread use of olefin metathesis, the evolution of metathesis catalysts towards air stability has become an area of significant interest. In this fascinating area of study, beginning with early systems making use of high oxidation state early transition metal centers that required strict exclusion of water and air, advances have been made to render catalysts more ...

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Light activation is a most desirable property for catalysis control. Among the many catalytic processes that may be activated by light, olefin metathesis stands out as both academically motivating and practically useful. Starting from early tungsten heterogeneous photoinitiated metathesis, up to modern ruthenium methods based on complex photoisomerisation or indirect photoactivation, this surve...

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ژورنال

عنوان ژورنال: Beilstein Journal of Organic Chemistry

سال: 2015

ISSN: 1860-5397

DOI: 10.3762/bjoc.11.221